Intermolecular adhesion in conducting polymers

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Intermolecular adhesion in conducting polymers.

We analyze the interaction of two conducting, charged polymer chains in solution using a minimal model for their electronic degrees of freedom. We show that a crossing of the two chains in which the polymers pass within angstroms of each other leads to a decrease of the electronic energy of the combined system that is significantly larger than the thermal energy and thus promotes interchain agg...

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ژورنال

عنوان ژورنال: Physical Review E

سال: 2005

ISSN: 1539-3755,1550-2376

DOI: 10.1103/physreve.71.051802